Remoción fotocatalítica de dqo, dbo5 y cot de efluentes de la industria farmacéutica

Autores/as

  • Alba Nelly Ardila Arias Politécnico Colombiano Jaime Isaza Cadavid
  • Juliana Reyes Calle Politécnico Colombiano Jaime Isaza Cadavid
  • Erasmo Arriola Villaseñor UAM Iztapalapa
  • José Alfredo Hernández Unidad Profesional Interdisciplinaria de Ingeniería-Campus Guanajuato UPIIG

Palabras clave:

Fotocatálisis heterogénea, aguas residuales, farmacéuticos, industria farmacéutica, efluentes industria farmacéutica, dióxido de titanio, materia orgánica

Resumen

Se evaluó la efectividad de la fotocatálisis heterogénea usando TiO2 en la remoción de la materia orgánica presente en el efluente de una industria farmacéutica. Los resultados reflejan que las variables investigadas (pH inicial del medio, cantidad de TiO2 y concentración de H2O2), afectan la eficiencia de remoción de la materia orgánica. Los mayores niveles de remoción de DQO (70.4%), DBO5 (96.7%) y COT (81.4%) se obtuvieron con 340 mg/L de TiO2, 10.0 mM de H2O2 y un pH inicial de 7.0, después de 5 horas de irradiación artificial.

Métricas de artículo

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Citas

Mohamed I. Badawy, Rifaat A. Wahaab, A.S. El-Kalliny. Fenton-biological treatment processes for the removal of some pharmaceuticals from industrial wastewater. J. Hazard. Mat., 167, 567–574, 2009.

Boroski M., Rodrigues C., Garcia J., Sampaio L., Nozaki J., Hioka N. Combined electrocoagulation and TiO2 photoassisted treatment applied to wastewater effluents from

pharmaceutical and cosmetic industries. J. Hazard. Mat. 162, 448–454, 2009.

Huseyin T., Okan B., Selale S. Ataberk, Tolga H., Haluk C., Dilek S., Filiz B., Ulku Y. Use of Fenton oxidation to improve the biodegradabilityof a pharmaceutical wastewater. J. Hazard. Mat., B136, 258–265, 2006.

Klamerth N., Miranda N., Malato S., Aguera A., Fernández A., Maldonado M., Coronado J. Degradation of emerging contaminants at low concentrations in MWTPs effluents with mild solar photo-Fenton and TiO2. Catal. Today, 144, 124–130, 2009.

Pérez L., Maldonado M., Gernjak W., Aguera A., Fernández A., Ballesteros M., Malato S. Decomposition of diclofenac by solar driven photocatalysis at pilot plant scale. Catal. Today, 101, 219–226, 2005.

Calza P., Sakkas V., Medana C., Baiocchi C., Dimou A., Pelizzetti A., Albanis T. Photocatalytic degradation study of diclofenac over aqueous TiO2suspensions. App. Catal.B: Environ., 67, 197–205, 2006.

Chong M., Jin B., Chow C., Saint C. Recent developments in photocatalytic water treatment technology: A review. Water Research, 44, 2997-3027, 2010.

INESCOP. (Diciembre de 2012). Aplicación de Bioensayos Respirométricos en Aguas de Tenerías. Recuperado el 20 de Junio de 2011, de www.inescop.es/0servidor0/inescop/.../Art%20Tec%20Respirometria.pdf.

Shiyun Z., Zheng Z., Daotang L., Weimin C. Ozonation of naphthalene sulfonic acids in aqueous solutions: Part II—Relationships of their COD, TOC removal and the frontier orbital energies. Water Res.,37, 1185–1191, 2003.

Yang H., Guiying L., Taicheng A., Yanpeng G., Jiamo F. Photocatalytic degradation kinetics and mechanism of environmental pharmaceuticals in aqueous suspension of TiO2: A case of sulfa drugs. Catal. Today, 153, 200-207, 2010.

Yang H., Taicheng A., Guiying L., Weihua S., William J., Cooper H., Xindong G. Photocatalytic degradation kinetics and mechanism of environmental pharmaceuticals in aqueous suspension of TiO2: A case of -blockers. J. Hazard. Mat., 179, 834-839, 2010.

Sakkas V., Calza P., Medana C., Villioti A., Baiocchi C., Pelizzetti E., Albanis T. Heterogeneous photocatalytic degradation of the pharmaceutical agent salbutamol in aqueous titanium dioxide suspensions. App. Catal. B: Environ., 77, 135–144, 2007.

S. Malato, P. Fernández-Ibanez, M.I. Maldonado, J. Blanco, W. Gernjak.Decontamination and disinfection of water by solar photocatalysis: Recent overview and trends. Catal. Today, 147, 1-59, 2009.

Almudena Aguinaco, Fernando J. Beltrán, Juan F. García-Araya, Ana Oropesa. Photocatalytic ozonation to remove the pharmaceutical diclofenac from water: Influence of variables. Chem. Engin. J., 189–190, 275-282, 2012.

Rizzo L., Meric S., Guida M., Kassinos D., Belgiorno V. Heterogenous photocatalytic degradation kinetics and detoxification of an urban wastewater treatment plant effluent contaminated with pharmaceuticals. Water Res. 43, 4070-4078, 2009.

L. Rizzo, S. Meric, M. Guida, D. Kassinos, V. Belgiorno. Heterogenous photocatalytic degradation kinetics and detoxification of an urban wastewater treatment plant effluent contaminated with pharmaceuticals. Water Res. 43, 4070-4078, 2009.

Meng Nan Chong, Bo Jin Photocatalytic treatment of high concentration carbamazepine in synthetic hospital wastewater. J. Hazard. Mat. 199–200, 135-142, 2012.

Meng Nan Chong, Bo Jin, Christopher W.K. Chow, Chris Saint. Recent developments in photocatalytic water treatment technology: A review. Water Res. 44, 2997-3027, 2010.

M.A. Sousa, C. Gonçalves, Vítor J.P. Vilar, Rui A.R. Boaventura, M.F. Alpendurada. Suspended TiO2-assisted photocatalytic degradation of emerging contaminants in a municipal WWTP effluent using a solar pilot plant with CPCs. Chem. Eng. J.198–199, 301-309, 2012.

I. Oller, S. Malato, J.A. Sánchez-Pérez. Combination of Advanced Oxidation Processes and biological treatments for wastewater decontamination A review. Sci. Total Environ., 409, 4141-4166, 2011.

Montgomery, D. C., Diseño y Análisis de Experimentos. Limusa Willey, México, 2008.

Klavarioti M., Mantzavinos D., Kassinos D. Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. Environ. Intern. 35, 402–417, 2009.

Vogna D., Marotta R., Napolitano A., Andreozzi R., D’Ischia M. Advanced oxidation of the pharmaceutical drug diclofenaco with UV/H2O2 and ozone. Water Res., 38, 414–422, 2004.

Hofmann J., Freier U., Wecks M., Hohmann S. Degradation of diclofenac in water by heterogeneous catalytic oxidation with H2O2. App. Catal. B: Environ. 70, 447–451, 2007.

Kotchen M., Kallaos J., Wheeler K., Wong C., Zahller M. Pharmaceuticals in wastewater: Behavior, preferences, and willingness to pay for a disposal program. J. Environ. Manag. 90, 1476–1482, 2009.

Taicheng An, Jibin An, Hai Yang, Guiying Li, Huixia Feng, Xiangping Nie. Photocatalytic degradation kinetics and mechanism of antivirus drug-lamivudine in TiO2 dispersion. J.f Hazard. Mat.197, 229-236, 2011.

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Publicado

2012-12-20

Cómo citar

Arias, A. N. A., Calle, J. R., Villaseñor, E. A., & Hernández, J. A. (2012). Remoción fotocatalítica de dqo, dbo5 y cot de efluentes de la industria farmacéutica. Revista Politécnica, 8(15), 9–17. Recuperado a partir de https://revistas.elpoli.edu.co/index.php/pol/article/view/316

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